herselfpronoun
Herself refers back to a woman, girl, or female animal already mentioned, either as the object of her own action or to show that she, no one else, did it.
reflexiveused as the object of a verb or preposition when the action affects a woman, girl, or female animal already mentioned, the same one who is the subject
Herself is used when the subject and the object of the same clause refer to the same female person or animal: she cut herself. It is not just another way of saying her: when the object is a different person from the subject, use her (he gave it to her).
for emphasisused after a noun or pronoun, or alone, to show that she, and no one else, did something or was affected
This emphatic use often comes right after the subject or at the end of the clause: she herself doesn't believe it; she painted the fence herself.
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Usage
In its reflexive use, herself is not simply a more polite or formal way of saying her: it refers back to the subject of the same clause. When the subject is someone else, use her: can you come with her?